| Analyse | Condition atmosphère inerte | Type de solides | Type de solution (molécule/réactions) | Instruments |
|---|
I/V Courant vs potentiel de 0 à 1 solaire d’irradiation.(automatisé ou manuel) | en boîte à gant | Dispositif: PV, OPV, DSSC (taille de 18 x 20 mm à 1″ carré) | n/a | Robot Solartrand (UdeM), Potentiostat SP-150 (Bio-Logic), Simulateur solaire Verasol-2 (AAA, DEL, Newport) |
| EQE/IQE Efficacité quantique externe/interne (350 à 1100 nm). (automatisé ou manuel) | en boîte à gant | Dispositif: PV, OPV, DSSC (taille de 18 x 20 mm à 1″ carré) | n/a | robot Solartrand (UdeM), IQE-200b (Newport) |
| EIS Spectroscopie d’impédance électronique jusqu’à 1 MHz. | en boîte à gant | Dispositif: DSSC (taille de 18 x 20 mm à 1″ carré) | n/a | Robot Solartrand (UdeM), Potentiostat SP-150 (Bio-Logic), Simulateur solaire Verasol-2 (AAA, DEL, Newport) |
| Spectroscopie d’absorption transitoire Deux instruments disponibles, couvrant les ordres temporels du picoseconde au milliseconde. Fenêtre optique de 300 à 900 nm, avec source laser ajustable. | en cuvette scellée | film, poudre ou dispositif (montage sur mesure) | volume de 3 mL et moins | LP980 (Edinbourg instruments) Axis-TRX (Axis Photonique Inc) |
Spectroscopie UV-vis-NIR Absorption, transmittance et réflectance spéculaire ou diffuse avec sphère d’intégration. Fenêtre optique de 200 à 1800 nm. | en boîte à gant via fibre optique ou en cuvette scellée | film, poudre ou dispositif, monté sur la sphère d’intégration | disponible aussi pour des suivis cinétiques ou de flux, combinable avec des techniques d’électrochimie | Cary6000i (Agilent) |
Spectroscopie de fluorescence Instrument smultiples, permettant mesures à l’état d’équilibre ou temporelles (temps de vie) et de rendement quantique. Température variable jusqu’à 77 K. | en boîte à gant via fibre optique ou en cuvette scellée | film, poudre ou dispositif | disponible aussi pour des suivis cinétiques ou de flux, combinable avec des techniques d’électrochimie | Cary Eclipse (Agilent) LS-55 (Perkin-Elmer), Mini-Tau (Edinbourg instruments) FLS-920 (Edinbourg instruments) |
| Spectroscopie infrarouge ATR ou transmittance. | en boîte à gant | film ou poudre | combinable avec des techniques d’électrochimie | Spectrum Two FT-IR (Perkin-Elmer) |
| (Spectro)Electrochimie Toutes les expériences standards d’électrochimie sont disponibles, incluant voltampérométrie cyclique, électrolyse et électrode rotative. | en boîte à gant ou en cuvette sous flux d’argon | Film ou dispositif | plusieurs format de verrerie disponible de 0.5 mL à 50 mL. | SP-150 (Bio-Logic) |
| Suivi GC pour H2, CO2, CO et CH4 (TON/TOF) Mesure de rendement et de fréquence des cycles catalytiques pour la génération de gaz permanent avec photoréacteurs spécialisés, pour photo- et électro- catalyse | en cuvette scellé ou sous flux d’argon | réaction hétérogène possible (i.e. avec catalyseur solide) | Volume de réaction de 1 à 15 mL, limite de détection sous l’ordre des ppm pour H2 et sous l’ordre des ppb pour CO2, CO et CH4. | Clarus 480 et 580 (Perkin-Elmer) |
Calculs Ab initio Optimisation de structures, analyse des propriétés spectrales et électroniques. | | | Calculé avec modèle PCM pour les effets de solvant | Gaussian2016 |
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